INFLUENCE OF DISPERSION NITRIDE VANADIUM STRENGTHENING ON THE TRIBOTECHNICAL AND MECHANICAL PROPERTIES OF HYPEREUTECTOID STEELS

Authors

  • S.Ya. Shipitsyn Physico-Technological Institute of Metals and Alloys of NAS of Ukraine, (Kyiv Ukraine) https://orcid.org/0009-0004-6406-5345
  • V.G. Novitskyi Physico-Technological Institute of Metals and Alloys of NAS of Ukraine, (Kyiv Ukraine)
  • G.E. Fedorov Physico-Technological Institute of Metals and Alloys of NAS of Ukraine, (Kyiv Ukraine)
  • T.V. Stepanova Physico-Technological Institute of Metals and Alloys of NAS of Ukraine, (Kyiv Ukraine) https://orcid.org/0009-0002-5489-9595
  • N.V. Kiryakova Physico-Technological Institute of Metals and Alloys of NAS of Ukraine, (Kyiv Ukraine) https://orcid.org/0009-0000-8220-1209

DOI:

https://doi.org/10.15407/plit2026.01.061

Keywords:

wear-resistant steel, dispersion vanadium nitride hardening, tribotechnical, mechanical properties, alloying

Abstract

Increasing the wear resistance of friction pair materials can be achieved by using more advanced compositions of lubricants, such as solid lubricants, which are extremely stable in difficult operating conditions. The combination of several components with sharply different physical and mechanical properties allows you to create compositions with the necessary properties. In such materials, films of plastic material are formed on the areas of the solid component, which are formed either due to the difference in the coefficients of thermal expansion of the antifriction and solid components when the friction pair is heated, or as a result of mechanical spreading. Such alloys include hypereutectoid steels, which contain graphite inclusions and copper inclusions in the matrix. This study identifies the mechanisms and patterns of the influence of doping hypereutectoid steels with nitrogen and vanadium on the effectiveness of increasing their wear resistance under various wear conditions due to “hard lubrication” with graphite and a copper phase while maintaining and increasing their structural strength and wear resistance. Three groups of steels were studied: the first standard with a carbon content of 1.5%; the second also standard with 1.5% carbon alloyed with 13% copper; the third with a carbon content reduced to 1.2%. It was found that dispersion vanadium nitride hardening reduces the intensity of wear in all three groups of steels. Also, in all cases, a reduction in the friction coefficient by 15–27% is achieved. This is the result of solid lubrication with carbon and copper, which accumulate on the friction surface and form a third body on the surface of the friction pair. An almost threefold increase in the efficiency of “solid lubrication with graphite” of steel №2 is observed, mainly due to an increase in the amount and dispersion of graphite in the structure due to the modifying action of solid-soluble nitrogen during crystallization and phase transformations of steels and dispersion of the dendritic micro- and substructure by the nitride-vanadium phase.

Author Biographies

S.Ya. Shipitsyn, Physico-Technological Institute of Metals and Alloys of NAS of Ukraine, (Kyiv Ukraine)

Dr. Tech. Sci., Lead Scientist

V.G. Novitskyi, Physico-Technological Institute of Metals and Alloys of NAS of Ukraine, (Kyiv Ukraine)

Cand. Tech. Sci., Prov. Sci. Assoc.

G.E. Fedorov, Physico-Technological Institute of Metals and Alloys of NAS of Ukraine, (Kyiv Ukraine)

Cand. Tech. Sci., Senior Sci. Assoc.

T.V. Stepanova, Physico-Technological Institute of Metals and Alloys of NAS of Ukraine, (Kyiv Ukraine)

Sci. Assoc.

N.V. Kiryakova, Physico-Technological Institute of Metals and Alloys of NAS of Ukraine, (Kyiv Ukraine)

Chief Tech.

References

Novitskyi V.G., Gavrilyuk V.P., Panasenko D.D., Kalchuk N.A., Khoruzhiy V. Ya. // Formation of friction layers and wear resistance of steels in the conditions of boundary friction. Physico-chemical mechanics of materials. 2003 . vol. 39, no. 6. Р. 81–87 [in Russian]. https://doi.org/10.1023/B:MASC.0000031651.48063.e9

Pavlyk B.B. Oshinya L.Ya., Sidorov S.Ya., Bobylev Yu.A. Changes in the structure, properties, and physical state of friction surfaces during runin. // Automation of production technical preparation. Riga. 1983. Р. 115–119 [in Russian].

Kanarchuk V. E. Adaptation of materials to dynamic effects. Kyiv: Nauk. Dumka. 1986. 265 p.

Fedorov V.V. Kinetics of damage and destruction of materials. Tashkent: Scientific Academy of Sciences, 1985. 175 p. [in Russian].

Kvasnytska Y. G., Tarasevich M. I., Grigorenko S. G., Kiryakova N. V., Oleksenko I. V. Peculiarities of structure formation of post-eutectoid steels doped with copper // Scientific and technical journal "Metalology and metal processing". 2024. No. 3. P. 50–60 [in Ukrainian].

Loktionov-Remizovsky V.A., Shipitsyn S.Ya., Novitsky V.G., Kiryakova N.V. The effectiveness of the influence of copper alloying on the wear of hypereutectoid steels. // Scientific and technical journal «Metallurgy and metal processing». 2022. No. 4. P. 33–38 [in Ukrainian].

Babaskin Yu.Z., Shipitsyn S.Ya., Kirchu I.F. Structural and special steels with nitride phase. – Kyiv: Nauk. dumka. 2005. 371 p. [in Russian].

Akimov. I.V. Increasing the wear resistance of graphitized steel. Science and progress of transport. Bulletin of the Dnipropetrovsk National University of Railway Transport. 2013, No. 6 (48). [in Russian]. https://doi.org/10.15802/stp2013/19678

Akimov I.V. Increasing the mechanical properties of cast graphitized steel. Science and progress of transport. Bulletin of the Dnipropetrovsk National University of Railway Transport, 2015, No. 3 (57) [in Russian].

Published

17-03-2026

How to Cite

Shipitsyn С. ., Novitskyi В. ., Fedorov Г. ., Stepanova Т. ., & Kiryakova Н. . (2026). INFLUENCE OF DISPERSION NITRIDE VANADIUM STRENGTHENING ON THE TRIBOTECHNICAL AND MECHANICAL PROPERTIES OF HYPEREUTECTOID STEELS. Casting Processes, 163(1), 61–69. https://doi.org/10.15407/plit2026.01.061

Issue

Section

NEW CASTING MATERIALS

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